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Friday, May 23, 2025

USGS Study: Geospatial Analysis of Water-Quality Threats from Orphan Wells in U.S. Aquifers: Study Review and AAPG Webinar Review

     Orphan wells are wells with no current owner. Typically, they are very old wells, but newer wells may be orphaned, too. The issue with orphan wells for groundwater is that they may provide a path for contaminants to enter groundwater aquifers. Both hydrocarbons and brine water are contaminant sources. Existing water quality data will often miss local contamination from orphan wells. The USGS scientists used geospatial and statistical methods to highlight areas of concern for potential groundwater pollution from orphan wells. Three factors were used: 1) number and density of orphan wells in an area; 2) factors that can threaten well integrity and contribute to contaminant transport; and 3) factors related to groundwater withdrawal rates and the affected populations/communities in the event of water quality disturbances. About half of the identified orphan wells can threaten principal aquifers, and the other half can threaten secondary aquifers. Three areas were defined as having the highest susceptibility to groundwater contamination from orphan wells:

1) The Appalachian Basin (including the Pennsylvanian Aquifer System), 2) The Gulf Coast Aquifers (including the Coastal Lowlands Aquifer system) and 3) The California Aquifers (including the California Coastal Basin Aquifer system).”











     Well age is a very good proxy for well integrity since old wells degrade more as time passes. Standards for casing wells were not developed until the 1950s, so wells older than that are particularly susceptible to loss of integrity. Well integrity loss can take a few different forms. Corrosive fluids can cause deterioration of casing, tubing, and the cement around the casing. If brine water migrates up from below, it can enter freshwater aquifers. The freshwater groundwater can also be corrosive, and this is a big factor in well integrity.

We further identified three eras to classify wells on a national scale: pre-1935 wells, which predate the Interstate Oil Compact Commission (IOCC) (which would go on to become the Interstate Oil and Gas Commission, IOGCC); 1935–1972 wells, which predate the Safe Drinking Water Act (Safe Drinking Water Act, 1974) and many regulations focused on protecting aquifer systems; and post-1972 wells, where regulatory frameworks typically include both environmental and oil and gas conservation concepts on a national scale (Nickolaus et al., 2009).”

     The location of orphan wells relative to coal seams was identified as an important factor. Mine subsidence, acid mine drainage, and coalbed methane releases can all affect well integrity.

     Aquifer properties can also affect contaminant transport. Aquifers with significant fracture porosity and those in limestone karst voids can transport contaminants faster and farther, and so are more susceptible to contamination.

     As noted, corrosivity is an important factor for potential contamination. They explain how they arrived at corrosivity susceptibility:

To derive this dataset, single point Langelier Saturation Indices (LSI), a metric for corrosivity, were compiled for groundwater samples from 20,962 locations in the United States from (Belitz et al., 2016a) and joined to each principal or secondary aquifer. The mean of these points within each AS were then computed and compared to each other.”

     Another factor is groundwater withdrawal rates. California has among the highest withdrawal rates due to population and agricultural use. Different aquifers have different sustainable yields, so withdrawal rates need to be normalized for the different yields of different aquifers.

     Along with corrosivity, the groundwater interacts chemically with casing metals and cement, which can make it more corrosive. Corrosion rates generally increase with lower pH and higher total dissolved solids (TDS) conditions.








     Aquifers that intersect surface water bodies and wetlands are of particular concern for aquifer contamination from orphan wells. Sensitive ecological systems can be damaged. Below are some land use categories for orphan well areas. Many old wells were drilled on land but are now underwater. Those wells are particularly challenging to plug, but they also have a higher potential for damaging contamination.






     The researchers combined susceptibility factors and withdrawal metrics to arrive at the areas most susceptible to contamination from orphan wells, as shown below.










     The researchers also acknowledged that information about orphan wells is still very limited, and this is problematic. They also think there could be other, as of yet, unidentified factors that could influence groundwater contamination from orphan wells.

     The AAPG webinar, presented by three authors of the paper, adds some additional information. They note that hydrocarbons in groundwater may be gaseous or dissolved in water. Gas will likely bubble out at atmospheric pressures but can present an explosion hazard. Leaks can kill surrounding vegetation. Hydrocarbons in groundwater can feed bacteria and lead to metals mobilization, such as iron and H2S formation from sulfate reduction. This can lead to more corrosion in the form of pipe scale or cement degradation. They also note that hydrocarbons and brines can occur naturally in groundwater, which can complicate analysis. Carbon and hydrogen isotope analysis can determine if gas in groundwater has a biogenic source or a deeper thermogenic source, which is associated with oil & gas development.

     The USGS released a dataset in 2024 of water quality within 1 mile of orphan wells. Parameters such as TDS, TSS, dissolved hydrocarbons, pH, temp, etc., are considered. The dataset is targeted at industry, policymakers, and researchers. Safety, well plug integrity, plug design vs. water quality parameters are all considered. Sulfate analysis is important since sulfate can attack well cement. Thus, cement recipes can be tweaked to help prevent corrosion in areas with known corrosive groundwater. The researchers also utilize a produced water geochemistry database to determine if brine is contaminating aquifers. They plan to release a paper on wellbore deterioration soon. 

     In some legacy wells in the Los Angeles Basin, there is groundwater entering the orphan wells. Cones of depression in those wells have likely been detected.

     Tools to assess wellbore integrity include downhole acoustics, which the USGS utilizes. Baseline water quality data, or pre-drill water quality data, is very important for linking contamination to oil & gas operations, even for orphan wells. Even very old, historical water quality data can be considered as a proxy for baseline data before the drilling of some orphan wells. Trying to understand why plugs fail or assessing plug integrity needs more study, since previously plugged wells can cause problems. The giant Texas sinkhole in the Permian region is an example where pressurized groundwater due to wastewater disposal in shallower zones, along with loss of well integrity, can lead to serious issues. The well around which the sinkhole occurs was plugged in the 1970s, but apparently, the plugs are not preventing groundwater from invading the well. New cementing recipes with clays, resins, and/or bio-cement can help improve plug integrity.  

   

     

 

 

References:

 

A geospatial analysis of water-quality threats from orphan wells in principal and secondary aquifers of the United States. USGS. May 10, 2025. A geospatial analysis of water-quality threats from orphan wells in principal and secondary aquifers of the United States | U.S. Geological Survey

A geospatial analysis of water-quality threats from orphan wells in principal and secondary aquifers of the United States, Joshua Woda, Karl B. Haase, Nicholas J. Gianoutsos, Kalle Jahn, and Kristina Gutchess. Science of The Total Environment. Volume 976, 10 May 2025, 179246. A geospatial analysis of water-quality threats from orphan wells in principal and secondary aquifers of the United States - ScienceDirect

USGS Geospatial Analysis of Water-quality Threats from Orphan Wells in Principal and Secondary Aquifers of the United States. AAPG Academy Webinar. May 22, 2025. 

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