Researchers at
ETH Zurich, led by Bill Morandi, Professor of Synthetic Organic Chemistry,
discovered a way, late last year, to convert some very toxic persistent organic
pollutants on-site into other captured chemicals and byproducts. They can do
this through electrolysis via alternating current and by utilizing
electrochemistry principles.
Persistent organic pollutants
(POPs) are chemically stable and can remain in soil, water, and organisms for
decades. These include some very toxic chemicals like the pesticides DDT and
lindane. POPs can also accumulate in fatty tissue and enter the food chain.
Several of these chemicals were banned long ago, but are still present in the
environment and in human blood.
The new research offers hope
that POPs can be remediated successfully.
"The key advance of this new technology is the use
of alternating current to sequester the problematic halogen atoms as innocuous
salts such as NaCl (table salt), while still generating valuable
hydrocarbons," says Morandi.
According to ETH Zurich:
“A key distinction between this and previous work is
that the carbon skeleton of the pollutants is recycled and made reusable, while
the halide component is sequestered as a harmless inorganic salt. “The previous
methods were also energetically inefficient,” says Patrick Domke, a doctoral
student in Morandi’s group. He explains: “The processes were expensive and
still led to outcomes that were harmful to the environment.”
Phys.org writes:
“Electrolysis enables almost complete dehalogenation of
pollutants under mild, environmentally friendly and cost-effective conditions.
It cleaves the stable carbon-halogen bonds, leaving behind only harmless salts
such as table salt and useful hydrocarbons such as benzene, diphenylethane or
cyclododecatriene.”
These useful hydrocarbons are
used in many ways in the chemical industry. Thus, the discovery also enables a
circular economy.
"Alternating current protects the electrodes from
wear, which is why we can reuse them for many subsequent electrolysis cycles.
In addition, the alternating current suppresses unwanted side reactions and the
formation of poisonous chlorine gas, allowing the pollutant's halogen atoms to
be fully converted to inorganic salts."
“The reactor used by the researchers consists of an
undivided electrolysis cell in which dimethyl sulfoxide (DMSO) is used as a
solvent—itself a by-product of the pulp process in paper production.”
The process can directly
treat soil and sludge without pretreatment or separation processes. A prototype
reactor has been tested successfully on DDT and lindane. It can be assembled
on-site. No hazardous substances need to be transported.
According to the Re Soil Foundation, this new technique could be employed for a variety of POPs as well as other contaminants that are stable in the environment, such as the so-called forever chemicals like PFAS/PFOA. They note EPA’s designation of “persistent” and compare “half-lives” of different stable chemicals:
References:
Can
electrolysis solve one of the biggest contamination problems? Walter Schmid.
Phys.org. November 25, 2025. Can electrolysis solve one of the
biggest contamination problems?
Electrolysis
can solve one of our biggest contamination problems. Walter Schmid, Corporate
Communications. ETH Zurich. November 25, 2025. Electrolysis can solve one of our
biggest contamination problems | ETH Zurich
Through
electrolysis we can neutralize (and enhance) soil contaminants. Matteo Cavallito. Re Soil Foundation.
December 22, 2025. Through electrolysis we can
neutralize soil contaminants






























