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Wednesday, December 10, 2025

The Vadose Zone - A Critical Indicator for Nebraska Groundwater Quality: Nitrate from Fertilization is the Primary Contaminant of Concern: Daugherty Water for Food Podcast, Episode 44: Summary & Review


       This podcast was moderated by Water for Food Podcast, host Frances Hayes. It was presented by Arindam Malakar, a researcher with the Nebraska Water Center, and Marie Krausnick, assistant general manager for Nebraska’s Upper Big Blue Natural Resources District (NRD).  

While nitrate levels in some areas have decreased in the Upper Big Blue NRD, there has been an overall increase of 54% in the district.”

     Nitrate is indicated as a water contaminant that can have significant negative health effects. When I worked for a county health department collecting private water system samples from newly drilled wells, we would use a strip to test for the presence of nitrates/nitrites. As this was not in a farming area, nitrate was never an issue. I only saw one sample that even registered the presence of nitrate, although it was too low to be of any concern.

Excess nitrate in drinking water can cause adverse health effects, particularly in infants and vulnerable populations, as too much nitrate in the body makes it harder for red blood cells to carry oxygen.”

     The vadose zone is the interval between plant roots and the top of the water table. The vadose zone is also considered to be the interval between the surface of the Earth and the groundwater table. It is the interface and conduit between the ground surface and the groundwater table. Contaminants from the surface may remain in the vadose zone for many years and decades. Long-term studies are necessary for determining how contaminants move through the vadose zone. Contaminants can move through a porous vadose zone, such as sand, in 3 to 6 years, but movement through loam and clay soils is much slower.




     Both biological and chemical reactions take place in the vadose zone. Knowing these reactions can point to remediation methods that will be successful.

     The Nebraska Water Center takes soil cores. Nitrates are a chief contaminant in Nebraska due to agriculture. This includes manure applications for growing crops as well as manure from grazing animals, manure ponds, CAFO feeding operations, etc. Vadose zone soil core collection began in the 1980s, and nitrate profiles can be developed for the vadose zone. The cores can reach about 100 feet in depth. The results of newer cores are compared to older ones in the same areas to develop an idea of how nitrates move and change in the vadose zone. Geoprobes are used to collect samples and then bring them back to the lab for analysis. They also collect groundwater samples from monitoring wells. The monitoring program involves rechecking areas after five years.

     One thing to determine is how fast groundwater and its contaminants move through the vadose zone. Modeling helps fill in the gaps between samples. Sampling and modeling lead to the prediction of groundwater quality. Nitrates are often oxidized to ammonium, and measuring them can be helpful in that the ammonium has less of a negative effect on groundwater quality. These reactions can be tweaked by speeding them up with recharge treatments utilizing beneficial microbes. Irrigation techniques and volumes can affect nitrate contamination.

     Vadose zone studies track nitrate loading and nitrate speed moving through it. Recharge studies are also required to know how fast groundwater moves from the surface to the aquifer.

     Natural Resource Districts (NRDs) in Nebraska are based on watersheds rather than counties. There are 12 areas of responsibility. There are 17 NRD districts in the state, but also subdistricts. Emphases vary based on geographic location and whether or not the Ogallala aquifer is present in the area. The Upper Big Blue NRD collaborates with the Nebraska Water Center and the University of Nebraska-Lincoln on groundwater studies focused mainly on nitrate contamination. Other contaminants besides nitrate are also observed in the vadose zone project, including uranium, which is present in the state.

     NRDs utilize their groundwater management plans and sample yearly, multiple times a year, or every three years, depending on results. A certain level of nitrate concentration triggers more sampling. There is a need to know the farmers’ fertilization and irrigation details. Agricultural, biochemical, and health researchers are also partnered in.

     Using water well data and vadose sampling together is useful to determine the nitrate loads in the vadose zone that are headed to the aquifer, and comparing it to the current groundwater quality. Land management practices need to be known and tweaked when necessary. They also collect some pore water samples. If they can connect specific land management practices to contamination, then they can know contamination-increasing practices vs. those that do not increase contamination. Till vs. no-till is one example of practices that might affect groundwater quality. In that case, tilling leads to more nitrate contamination

     The state utilizes a credit system that is devised to decrease nitrate loads. One is to utilize the nitrate in the vadose zone by pumping it back up to be reused as fertilizer.

     Nebraska has about 40 years of vadose zone sampling. Aside from nitrate, as noted, other contaminants are studied. These include other forms of nitrogen that may be formed in the vadose zone. Nitrate loss and leaching need to be better understood. The state is ahead of nearby states in nitrate studies. Nebraska has a comprehensive and holistic approach that exceeds that of other states, especially its long-term vadose zone research, which other states are utilizing to better understand their own vadose zone issues. Vadose zone research is also picking up around the world, with China, New Zealand, and the EU leading with papers being published. Earlier studies focused more on how quickly nitrate moved through the vadose zone. More recent focuses have been on co-contamination, including nitrogen and nitrate reaction byproducts. The data is shared publicly. The Nebraska Water Center has an interactive map where specific data can be pulled up by site. It is linked in the Nebraska Vadose Zone link below in the references.

   




                       

                       Nebraska Vadose Zone Program

 

 

References:

 

The Vadose Zone - A Critical Indicator for Nebraska Groundwater Quality: Daugherty Water for Food Podcast, Episode 44. July 30, 2025. Daugherty Water for Food Podcast: 44 - The Vadose Zone - A critical indicator for Nebraska groundwater quality

Vadose Zone. University of Nebraska-Lincoln. Nebraska Water Center, Nebraska Vadose Zone | Nebraska

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