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Wednesday, August 21, 2024

Solid and Hazardous Waste Management: Overview and Current Issues


     We humans create significant amounts of solid waste and hazardous waste. That waste stream has varied through time and continues to vary as technology and materials use change. We deal with solid waste in three main ways: sanitary landfills, incineration, and reuse/recycling. Hazardous waste may be disposed of in special landfills or may be injected into wastewater disposal wells. Landfills also emit methane that may be captured, used, processed into renewable natural gas, and sold. They also produce CO2 and toxic gases. Landfills also produce toxic leachate that can enter groundwater aquifers. There has long been a debate about whether recycling or landfilling is better for the environment, but it is also clear that both will continue at robust levels.

     Solid waste is classified into three types: 1) Municipal solid waste, 2) Special waste, and 3) Hazardous waste. Municipal solid waste is basically residential and commercial trash. Special waste may be of seven types: 1) Medical waste, 2) Construction debris, 3) Asbestos, 4) Mining waste, 5) Agricultural waste, 6) Radioactive waste, and 7) sewage sludge. Medical waste is dangerous to workers and the public because it contains infectious agents. Healthcare workers have the highest exposure potential. Needles and other ‘sharps’ are a major avenue of exposure. Transmission of Hepatitis B and C and HIV are major concerns. Construction debris may be disposed of in special construction materials landfills or in municipal solid waste landfills. Like construction debris, asbestos is regulated separately. It has specific disposal requirements to minimize airborne asbestos fibers that cause lung disease. Mining waste volumes exceed the volume of all other solid wastes combined. Mining wastes can be sources of acid mine drainage and heavy metals. Agricultural waste has become more concentrated in industrial-scale farming localities.

     Hazardous waste is waste that has the potential to harm human health and ecosystem health. The U.S. EPA Resource Conservation & Recovery Act (RCRA) has specific classifications of hazardous waste. Hazardous waste is defined in two ways. First is a listing of about 500 types of industrial waste, often from specific processes. The way it is defined is through EPA criteria for specific properties of the waste such as ignitability, corrosiveness, reactivity, and toxicity. Exclusions from hazardous waste designation are given to oilfield wastewater and hazardous household chemicals.

 

 

Waste Stream Reduction: Mainly Recycling

 

     Waste management strategies include waste stream reduction. Recycling and substitution of materials and changing consumer habits are common ways to reduce the waste stream. Recycling and circular economies can be developed for industrial and municipal waste.

     Certain types of waste can be challenging. Used tires can be landfilled but often float upward and cause problems. Tires stored in open dumps can breed mosquitoes and tire fires once ignited are difficult to extinguish. The ash can leak toxins which can be carried into surface water and groundwater. Therefore, tire recycling is desirable. Counties and solid waste districts often handle tire recycling opportunities for residents and businesses. Unfortunately, tire recycling, like most forms of recycling, is often uneconomic or marginally economic. However, since waste reduction is a clear public good, recycling programs should continue, funded by both private and public sources.

 

 

 

Sanitary Landfills, Industrial, and Hazardous Waste Landfills

 

     Sanitary landfills replaced the open dumps of the past that were known for pest vectors, noxious odors, and easily mobile contaminant potential. Landfill site selection involves groundwater, surface water, and soil evaluation. Topography is also a consideration. Then grading can begin. Erosion and sediment control is then established. An under-barrier is installed to keep leachate water from percolating down into groundwater aquifers. Landfill leachate can be quite concentrated and toxic. Leachate collection and treatment systems are installed. Monitoring wells may be drilled to determine if leachate has entered groundwater. Leachate monitoring wells are drilled adjacent to cells close to the cell depth and groundwater monitoring wells are drilled deeper into aquifers. Landfills work by setting up waste cells. The waste is received, compacted, and covered with soil frequently, usually daily. Industrial or hazardous waste landfills are similar but much more heavily regulated. Often these waste streams are specific and have specific preparation, treatment, and/or packaging requirements before they are buried.

 


 






The map below shows where facilities are in the U.S. This includes ~14,300 large quantity generators (LQGs), ~ 46,000-60,000 small quantity generators ((SQGs), and ~ 900  treatment, storage, and disposal facilities (TSDFs). It does not include ~ 300,000- 470,000 conditionally exempt SQGs.







Waste Incineration and Waste-to-Energy

 

     Most forms of waste have been incinerated. Many facilities capture energy for use. These are waste-to-energy plants. Incineration reduces the amount of waste being processed. Completeness of combustion is a consideration at incinerators. This is ensured by the three T’s: 1) Time – how long the waste and its combustion gases are in the burn chamber, 2) Temperature – amount of energy needed to break molecular bonds and complete the combustion reaction, and 3) Turbulence – agitation of solids and combustible by-products that leads to more complete oxidation. Oxygen is added as combustion air. There are different incinerator designs that often use multiple chambers for primary and secondary combustion.

     Emissions from incinerators can be quite toxic. Now they are more strictly regulated, requiring pollution abatement equipment such as electrostatic precipitators, venturi scrubbers, and baghouses to capture fine particulate matter. Wet or caustic scrubbers control acid gas. Activated carbon filtration systems began to be installed around 20 years ago. These minimize products of incomplete combustion (PICs) like polyacrylic hydrocarbons (PAHs) and dioxins. Heavy metals such as mercury, cadmium, lead, and chromium are more difficult and expensive to abate.

 





 


Deep Well Injection

 

    Some waste, usually oil & gas brines, but also hazardous waste and radioactive waste may be injected into deep wells into saline reservoirs. EPA has a specific classification and specific construction and content requirements for these wells. There are different classes for different kinds of waste.

 

 

Other Waste Treatment Technologies

 

     Research into waste treatment is always ongoing. Treatments such as “supercritical water oxidation, molten metals and molten salt oxidation, glass melt and vitrification processes, and waste-specific biological treatment systems and composting.” Thermal desorption is used for old industrial waste.  

 

 

Health Concerns from Solid and Hazardous Waste

 

     The textbook Environmental Health: From Global to Local, edited by Howard Frumkin (2005), of which part of this post is a summary, gives five specific health concerns of solid and hazardous wastes:

 

1.        Risks of infectious disease from poorly managed solid waste

2.        Contamination of drinking water by biological and chemical wastes

3.        Formation of air pollutants in landfills

4.        Emission of air pollutants from incinerators

5.        Contamination of food by waste chemicals that escape into the environment

 

 

Old open dumps had dangerous levels of dangerous pests and without liners, they leaked leachate into groundwater. Modern sanitary landfills have largely improved those issues. Chemical reactions occur in landfills. As microbes decompose garbage and organic waste, organic acids are produced, making metals in the waste stream more soluble. Dangerous contaminants like volatile organic compounds (VOCs), industrial solvents, and petroleum distillates are often found in landfills. Of course, the methane and CO2 released from landfills contribute to climate change. The air emissions from landfills are roughly just less than 50% methane and just less than 50% CO2 with small amounts of other gases.  

     The book, from 2005, notes that 10% of hazardous waste is shipped across international borders. This must also be monitored and regulated. The Basel Convention regarding the transport of hazardous waste was ratified in May 2005 but not by the U.S. They stated that it needed to be approved by Congress in the Resource Conservation and Recovery Act would have to be updated. The issue is of concern because many countries do not have adequate training and capabilities to process hazardous waste. Lead-acid battery recycling facilities are one example of a dangerous facility due to airborne lead dust pollution that has devastated children in Africa, Mexico, and other places.

     Sometimes health concerns can come from poorly managed solid waste facilities. Municipal recycling facilities (MRFs) are susceptible to fires that can emit toxic smoke. Landfills could have unforeseen erosion and sedimentation issues or leachate migration issues. Natural disasters can generate significant amounts of solid waste such as when houses and buildings are damaged. Both destruction and construction debris are generated from the initial cleanup phase through the rebuilding phase as shown below.

 

 





Global Waste Management Data and Trends

 

     The World Bank provides some useful global information and data on solid waste management. In 2018 they estimated that about 90% of global solid waste is either burned or disposed of in open landfills. Open landfills and e-waste are concerning for a number of reasons, and I plan to do a separate post about that issue. Developed wealthy countries have better waste management systems than developing countries. Waste management is thus a capability enabled by wealth as well as the recognition of the importance of public health. The graphs below show some of the global waste management data and forecasts.  

 



















EPA Rules on Solid and Hazardous Waste: RCRA, CERCLA, EPCRA, TRI

 

RCRA

     The Resource Conservation and Recovery Act (RCRA) gives the EPA regulatory authority over solid and hazardous waste from when it is generated to post-disposal monitoring. RCRA is Congressionally mandated. The EPA provides guidance in the form of “explicit, legally enforceable requirements for waste management.” RCRA has been amended several times with required approval by the U.S. president. It was originally passed in 1976 with amendments added in 1984, 1992, and 1996. Subtitle D deals with non-hazardous solid waste and regulatory authority for managing it is given to the states under EPA guidance. Subtitle C deals with hazardous waste. The EPA may defer to states to regulate hazardous waste if the state is deemed capable.

Subtitle C regulations set criteria for hazardous waste generators, transporters, and treatment, storage and disposal facilities. This includes permitting requirements, enforcement and corrective action or cleanup.

RCRA has been amended and updated many times and continues to evolve. The Coal Combustion Residuals (CCR) rules were finalized in 2015, for example. The amendments are shown below.






     RCRA requires groundwater monitoring around landfills. Monitoring wells are drilled into aquifers near the landfill and the water is tested regularly. Soil vapor probes or shallow boreholes may be drilled to test for the presence of leachate outside the landfill boundaries. If leachate is found to be present, then corrective actions must ensue. The ability to pay for closure and post-closure of landfills must also be demonstrated by the owners. According to EPA:

In order to predict whether any particular waste is likely to leach chemicals into ground water at dangerous levels, EPA designed a lab procedure to estimate the leaching potential of waste when disposed in a municipal solid waste landfill. This labprocedure is known as the Toxicity Characteristic Leaching Procedure (TCLP).”

 

     “The TCLP requires a generator to create a liquid leachate from its hazardous waste samples. This leachate would be similar to the leachate generated by a landfill containing a mixture of household and industrial wastes. Once this leachate is created via the TCLP, the waste generator must determine whether it contains any of 40 different toxic chemicals in amounts above the specified regulatory levels (see Figure III-7). These regulatory levels are based on ground water modeling studies and toxicity data that calculate the limit above which these common toxic compounds and elements will threaten human health and the environment by contaminating drinking water.”

     Since wastes are often mixed with other waste, there is also a mixture rule that requires any amount of hazardous waste mixed with any amount of non-hazardous waste to be designated as hazardous waste. There is also the derived-from rule which covers hazardous waste residues often derived from the initial treatment of hazardous waste. These rules are described below.












          RCRA also covers hazardous waste recycling, recordkeeping, and reporting requirements. EPA’s RCRA Orientation Manual is a useful resource for assessing RCRA compliance. Hazardous waste transport, storage, and treatment all have RCRA requirements. Preventive measures such as drip pads, secondary containment for tanks, leachate leak detection, and spill response plans are required. There are specific rules for surface impoundments, such as those that hold coal combustion residuals, or coal ash slurry ponds. There are also air emission rules for landfills and other waste facilities. The table below shows different technologies that may treat hazardous waste. The second table shows the regulatory status of secondary materials











     Land disposal and combustion are two ways hazardous wastes are managed. Each has specific requirements that vary depending on the type and composition of the waste. Permitting hazardous waste storage, treatment, and disposal facilities has specific requirements and protocol as shown below.





     Corrective actions, or remediation, of hazardous wastes is also covered under RCRA. According to EPA:

Remedy implementation typically involves detailed remedy design, remedy construction, remedy operation and maintenance, and remedy completion. In the corrective action program, this step is often referred to as Corrective Measures Implementation (CMI)

     Compliance monitoring through periodic inspections and data collection and analysis are the methods of RCRA enforcement. Below are shown the different categories of enforcement inspections such as routine RCRA inspections, groundwater monitoring, and O&M inspections for monitoring wells.   

 






CERCLA

     The Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA), commonly known as Superfund, was enacted by Congress in 1980. CERCLA is sometimes referred to as the hazardous waste cleanup program. While RCRA covers hazardous waste generation, storage, treatment, and disposal, its final remediation is covered under CERCLA. According to the EPA:

This law created a tax on the chemical and petroleum industries and provided broad Federal authority to respond directly to releases or threatened releases of hazardous substances that may endanger public health or the environment. Over five years, $1.6 billion was collected and the tax went to a trust fund for cleaning up abandoned or uncontrolled hazardous waste sites.”

CERCLA “established prohibitions and requirements concerning closed and abandoned hazardous waste sites; provided for liability of persons responsible for releases of hazardous waste at these sites; and established a trust fund to provide for cleanup when no responsible party could be identified.”

Two kinds of remedial action were distinguished based on priority: short-term removals and long-term remedial response actions. CERCLA had some amendments added in 1986. The National Contingency Plan (NCP) is a part of CERCLA that requires planning for hazardous waste releases. CERCLA requires site investigations to determine the best remediation technology to utilize. According to the EPA:

CERCLA authorizes cleanup responses whenever there is a release, or a substantial threat of a release, of a hazardous substance, a pollutant, or a contaminant, that presents an imminent and substantial danger to human health or the environment.”

 














EPCRA and TRI

     The Emergency Planning and Community Right-to-Know Act (EPCRA) was passed by Congress in 1986 to deal with hazardous waste releases into the environment. It requires planning for the accidental release of toxic materials, or contaminants. It requires identifying where hazardous substances are generated, transported, and disposed of and assessing potential risks to public health in the event of a release. Community emergency response plans are developed.

    EPCRA requires that certain industrial facilities annually report estimates of quantities and types of hazardous waste stored onsite, treated onsite, and released to the environment. EPA uses this data to maintain its Toxic Release Inventory (TRI).

 

 

Waste Management Financing and Oversight: Budgets, Cost-Recovery, and Solid Waste Districts

     Waste management at the municipal level is funded by trash removal customers and by state, county, and local governments. EPA puts the minimum solid waste management costs in low-income countries for collection, transportation, and disposal in sanitary landfills at $35 per ton (2014). Adding advanced approaches like waste treatment and recycling the costs can be $50-100 per ton or more. For cities, solid waste management often makes up 4% to 20% of the municipal funds. Local governments provide about half of the required investments for waste services, with the rest typically provided through national government subsidies and the private sector. Capex and Opex are the two main cost requirements. Capital is required to build landfills, to buy and maintain trucks, and to buy dumpsters and bins. Labor, fuel, and equipment maintenance costs are an important consideration. Operational costs can be challenging and often make up 70% or more of solid waste operating budgets. Typical costs are shown below.

 





Costs for incinerators and anaerobic digestors are given below. It can be seen that incinerators are roughly comparable to landfilling costs. “Construction and operation of anaerobic digestion and incineration systems require a large budget and high management and technical capacity.”






The World Bank writes:

Waste management investment costs and operational costs are typically financed differently. Given the high costs associated with infrastructure and equipment investments, capital expenditures are typically supported by subsidies or donations from the national government or international donors, or through partnerships with private companies. About half of investments in waste services globally are made by local governments, with 20 percent subsidized by national governments, and 10–25 percent from the private sector, depending on the service provided.”

In high-income countries, there is better solid waste management and continuous improvement. Leachate collection systems, biogas capture and use, and functional recycling supply chains are common. Captured biogas may be processed into renewable natural gas.

     In the U.S. many states have solid waste districts, usually at the county level or a district may encompass multiple counties. These districts are tasked with planning and management of solid waste. They collect data, develop plans, have regular meetings, produce reports, and assess fees guided by the state. 




Public Participation, Input, and Opposition

     As noted, the permitting process provides for a public comment period when a facility is undergoing the permit process. Public hearings are also a part of that process. The public participation part of permitting is shown below.






     Public opposition can spring up when there are health concerns from the public or when new waste is added to an existing waste facility. A recent case is where a special hazardous waste landfill in Michigan was approved to accept low-level radioactive waste from atomic bomb byproducts from the 1940s Manhattan Project. It is the same landfill that accepted most of the dug-up waste from the East Palestine train derailment. Many local residents are opposed to radioactive waste being delivered. I think they are generally misinformed since adequately disposed of low-level radioactive waste is unlikely to cause any problems.

 


Reducing So-Called Climate Pollution

     EPA also helps to fund so-called climate pollution mitigation. Although I don’t like the term climate pollution since greenhouse gases are not like other pollutants, the mitigation path is often similar to other air pollution mitigation. Capturing methane from landfills is one feature. Landfills also produce CO2 which may be captured as well but I don’t believe any landfills capture and store CO2 since it is a smaller part of the waste stream than in combustion. Capturing the methane for use and to mitigate greenhouse gases is important. A lesser step is flaring methane since burning methane produces less global warming potential than venting it. EPA’s Climate Pollution Reductions Grant Program has access to a $4.2 billion fund set aside for climate pollution mitigation. This includes methane capture and utilization at landfills, organics recycling, clean collection fleets, food waste reduction, processing, and composting. Facilities may apply for the grants but may not be selected. So-called low-hanging fruit like methane capture and leak detection and repair (LDAR) is prioritized since it can have the biggest emissions reduction effects at the lowest cost. Oil and gas facilities, landfills, and natural sources of methane are targeted.  

 

 

References:

 

Environmental Health: From Global to Local. Chapter Nineteen. Solid and Hazardous Waste. Sven Rodenbeck, Kenneth Orloff, Harvey Rogers, and Henry Falk. Howard Frumkin, editor. Wiley & Sons. 2005.

How agencies in 6 states plan to spend millions from EPA climate pollution grants. Jake Wallace. Waste Dive. August 8, 2024. How agencies in 6 states plan to spend millions from EPA climate pollution grants | Waste Dive

Trends in Solid Waste Management. The World Bank. 2024. Trends in Solid Waste Management (worldbank.org)

What a Waste: An Updated Look into the Future of Solid Waste Management. World Bank Group. September 20, 2018. What a Waste: An Updated Look into the Future of Solid Waste Management (worldbank.org)

What a Waste 2.0: A Global Snapshot of Solid Waste Management to 2050. Silpa Kaza, Lisa Yao, Perinaz Bhada-Tata, and Frank Van Woerden. With Kremena Ionkova, John Morton, Renan Alberto Poveda, Maria Sarraf, Fuad Malkawi, A.S. Harinath, Farouk Banna, Gyongshim An, Haruka Imoto, and Daniel Levine. World Bank Group 2018. 9781464813290.pdf

Resource Conservation and Recovery Act (RCRA) Laws and Regulations. U.S. EPA. 2024. Resource Conservation and Recovery Act (RCRA) Laws and Regulations | US EPA

Resource Conservation and Recovery Act (RCRA) Laws and Regulations. Final Denial of Non-Hazardous Secondary Materials Rulemaking Petition. October 18, 2023. Final Denial of Non-Hazardous Secondary Materials Rulemaking Petition | US EPA

Resource Conservation and Recovery Act: Critical Mission & the Path Forward. U.S. EPA. June 2014. RCRA's Critical Mission and the Path Forward

RCRA Orientation Manual 2014. U.S. EPA. RCRA Orientation Manual: Table of Contents and Foreword (epa.gov)

Small town erupts as landfill will process radioactive waste. Alyssa Guzman. Daily Mail.  August 20, 2024. Small town erupts as landfill will process radioactive waste (msn.com)

Solid Waste Management Planning. Ohio EPA. Solid Waste Management Planning | Ohio Environmental Protection Agency

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