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Thursday, August 15, 2024

Industrial Heat Pumps: Varieties, Low Carbon Process Heat, Refrigerant Blends, Geothermal Apps, and Market Forecast


     One major avenue for industrial decarbonization is replacing the direct burning of fossil fuels with industrial heat pumps for process heat. This is one of the main methods of industrial electrification. Industrial heat pumps are deployed for low-temperature and high-temperature applications. Industrial heat pumps can also help decarbonize district heating. About 95% of industrial boilers are powered by fossil fuels (85%) and biomass (10%). Currently heat pumps provide 5% of global industrial heat. That is set to grow.  By 2030 they are expected to supply 10% of global low and medium-temperature industrial heat. or heat below 200 degrees C. They can be used in many kinds of industries, such as breweries, chemical plants and refineries, food and beverage, and pulp and paper industries. they can be used at different temperature ranges. Use cases can vary considerably depending on the project. Global investments are estimated to be between $12 billion and $21 billion by 2030. A March 2024 McKinsey & Company report notes:

 

The trajectory of these investments is toward bigger installations. Today, the majority of investments in industrial heat pump installations go toward smaller and medium-size applications (up to five MWth) and temperatures from 80°C to 100°C because lower-temperature applications are more likely to provide a positive business case. However, large-scale industrial heat pumps (more than five MWth) with temperatures higher than 100°C are expected to become increasingly important in the future. District heating is also expected to remain an important segment for industrial heat pumps, at more than a third of the market in 2030.”

 






     Industrial heat pumps can be defined as heat pumps with power sizes beyond 200 kilowatts thermal (kWth). Heat pumps are powered by electricity, which may be low-carbon electricity. They can be a ‘no-brainer’ for low-heat and medium-heat applications where they can be 3 to 5 times more efficient than traditional boilers. Thus, they can be a good efficiency investment, with savings down the line after upfront costs are recaptured. This eventual cost advantage combined with the decarbonization benefits of heat pumps is leading to growth in industrial heat pump manufacturing and deployment. McKinsey and Company expect annual growth to remain above 15% through 2030. Industrial heat pumps are incentivized for their low-carbon attributes as well. The EU plus the UK is the major demand and growth market for industrial heat pumps. High European natural gas prices in 2022-2023 made heat pumps more competitive and along with the urge to decarbonize, are keeping the market going and growing.







     As in residential heat pumps, the sources for the heat to be exchanged may be air, surface water, groundwater, soil, or rock. External heating may be added where applicable. An article in Thermal Engineering lists 12 types of industrial heat pumps, as described below.

 


Types of High-Temperature Industrial Heat Pumps (>70 degrees C)

 

1.        Compression Heat Pumps: These pumps use mechanical energy to compress a refrigerant, which then heats up as it is compressed. Variants include air-source, water-source, and ground-source compression heat pumps.

2.        Absorption Heat Pumps: Utilizing a heat source, such as natural gas or solar energy, these pumps rely on an absorption cycle involving a refrigerant and an absorbent fluid, commonly used where waste heat recovery is viable.

3.        Exhaust Air Heat Pumps: Specifically designed to recover heat from exhaust gases in industrial settings, these pumps are effective in reducing energy consumption and environmental impact.

4.        Steam Compression Heat Pumps: These pumps elevate the pressure and temperature of steam, making it suitable for processes like sterilization or heavy cleaning.

5.        Gas Compression Heat Pumps: Similar to steam compression, these devices compress gases other than steam, adapting the temperature and pressure to specific industrial needs.

6.        High-Temperature Heat Pumps: Capable of reaching temperatures up to 150°C, these are used in processes requiring significant heat, such as drying and curing operations.

7.        Cogeneration Heat Pumps: These systems combine heat and power generation, utilizing the waste heat from electricity production to enhance overall efficiency.

8.        Chemical Heat Pumps: These use chemical reactions to absorb or release heat, providing energy savings and environmental benefits.

9.        Desiccant Heat Pumps: Ideal for operations requiring humidity control, these pumps combine moisture absorption properties with heat pumping.

10.   Solar-Assisted Heat Pumps: Incorporating solar energy to reduce electricity usage, these systems are both sustainable and cost-effective for daytime industrial operations.

11.   Geothermal Heat Pumps: Using the stable temperatures of the ground or water sources, geothermal pumps are highly efficient for both heating and cooling purposes.

12.   Hybrid Heat Pumps: Integrating features of different heat pump types to optimize performance and efficiency according to specific application requirements.

 

 

     Low and medium-heat industrial heat pumps are considered to be mature technologies, but high-temperature industrial heat pumps are not yet considered mature. The McKinsey & Company report lists five considerations of industrial heat pumps worth considering, summarized below:

 

1.      There is no one-size-fits-all solution for industrial and district heating – differences in parameters like temperature, capacity, physical size, and integration into existing equipment are common. There is often a need for modifications and customization. Design and installation training will be important to develop more expertise in modifying and customizing industrial heat pump applications. Heat pump original equipment manufacturers (OEMs) need a better understanding of use cases and end-users need a better understanding of the technology. Another consideration is that those who operate fossil fuel or biomass-powered district heating systems may not be competent in operating heat pump systems.

 

2.      A high-performing industrial heat pump is more than just a compressor – Heat pump performance is determined by the compressor, heat exchangers (condenser and evaporator), and control software. Compressors control refrigerant flow rates and compression efficiency. Compressors can be complex and typically account for 20-35 % of overall hardware CAPEX. While compressors get the most attention, heat exchangers and control software can also increase efficiency and ensure that coefficients of performance (COPs) are up to standards. Smart controls can optimize performance and help with predictive and preventive maintenance. Standardization and modularization can also help the industry reduce costs.

 

3.      The race is still on between natural and synthetic refrigerants – The choice of refrigerant can vary depending on project type, size, and where it is built. They explain:

 

There are two groups of refrigerants: hydrofluorocarbons (HFCs) and hydrochlorofluorocarbons (HCFCs), and natural refrigerants. Some OEMs focus on only one group of refrigerants, whereas others have both groups in their portfolio (sometimes for historical reasons). While HFCs and HCFCs have been widely used in the past, there is a trend, especially in Europe, toward natural refrigerants because of (potential) environmental regulation, such as the F-gas quota limiting the use of fluorinated refrigerants with high global warming potentials (GWPs).”

 

Natural refrigerants include hydrocarbon gas liquids (aka natural gas liquids) such as propane, isobutane, and isopentane. These are flammable. They are applicable in many situations and have a much lower GWP than any of the F-gases. They mention some other common refrigerants and ongoing research:

 

Ammonia, which is widely used for refrigeration applications, is toxic, but it allows for very efficient thermodynamic cycles with zero ozone depletion or global warming potential. CO2 typically requires a transcritical cycle with high pressures and is best suited for applications where large temperature increases are needed. CO2 gains attractiveness in refrigeration as well as heating applications because it is nontoxic, nonflammable, and nonfluorinated. Water is an interesting refrigerant for high-temperature applications (steam compression), but evaporation must be run in vacuum for source temperatures below 100°C. Today, these and other alternative refrigerants are being researched and subsidized.”

 

4.      The most attractive use case combines heating and cooling demand – Being the owner of a heat pump I can attest to this as my electric use from A/C is very low. Combined heating and cooling apps can be useful in the food and beverage industry and for combining different buildings and facilities for shared systems. Heat pumps can be integrated with waste heat recovery and transfer among different end-users. Heat pumps can be integrated with district heating and with thermal energy storage, which can be used for power demand response.

 

5.      OEMs, end users, and engineering, procurement, and construction firms need to collaborate to create the best solutions – OEMs need to develop standardization and modularization, which requires deeper knowledge of each specific industry. They recommend “continued R&D with an emphasis on design to value.” End-users and design engineers should collaborate more, they say, especially on developing use cases. Engineering, procurement, and construction (EPC) firms can leverage their industrial heat pump installation expertise and their relationships with end users to help develop optimized solutions. New sales models such as off-the-shelf solutions, rentals, and support and maintenance agreements can be incorporated. In many cases, heat pumps will be retrofitted, which often requires customized solutions that this collaboration can facilitate. The goal of this collaborative approach is better integration of design, manufacturing, installation, and end-use.

 

     A 2016 paper in Applied Energy discusses industrial heat pump technology and research in China “including advances in refrigerants, multistage system, double-effect absorption system, compression–absorption system, solar assisted system, and chemical heat pump system.” The paper also gives some general information about different industrial heat pump cycles.

 

There are several heat pump cycles in industrial applications. These cycles can be divided into the following categories: vapor compression cycle (mechanical compression cycle), mechanical vapor recompression cycle, thermal vapor recompression cycle, absorption cycle, and chemical heat pump.”

 

     Siemens Energy is a major manufacturer of industrial heat pumps. They list the benefits of industrial heat pumps:

More efficient than direct conversion of electric power to heat

Simultaneous production of heat and cold due to thermal action

CO2-free and free of emissions, when power from renewable sources is used

Low levelized life-cycle cost of heat: Long term economic solution with low CAPEX and OPEX

Easy to integrate in existing processes and applications

Proven, reliable technology: Regular heat pumps are commonly available and attached to households. Large industrial heat pumps are being up-scaled and continuously improved and optimised by us.

Waste heat can be re-used and sold for other purposes, connecting different applications (enabling new business models)

Dynamic operation: Short ramp rates

Power grid stabilization: Peak shaving for excess power generation to balance supply and demand, surplus power from renewable sources can be converted into heat

In Europe in particular, the use of curtailed renewable energy to generate thermal energy storage reserves and the development of waste heat recovery and transfer technology is in development.

 



The new river heat pump from MVV supplies climate-friendly heat from Rhine water to around 3,500 households - One of the largest heat pumps of its kind in Europe.

 


 




Refrigerant Blending

 

     In order to utilize different temperatures for different industrial processes on the same system, it was traditional to use a different heat pump for each process. The new technology of blending refrigerants on the fly for different processes offers a way to use the same heat pump for different temperature applications. This solution has been developed by researchers from ETH Zurich and the Eastern Switzerland University of Applied Sciences in Buchs as a way to make heat pumps more flexible and to save money. The researchers note in their recent paper in the International Journal of Refrigeration: 

 

Some industrial heat pump applications come with challenges very different from residential heat pump applications, among them very high heat sink temperatures, the generation of steam or overcoming large temperature changes in the heat source and heat sink. For large temperature changes in heat source and sink, zeotropic mixtures have been proposed because of their glide which can match the temperature profile of the secondary fluids given counterflow heat exchange arrangements and possibly improve the COP significantly.”

 





Some of the mixtures analyzed in the past and present are in the table below. In the second table below are the pure and blended refrigerants tested in the study. They showed that the mass fraction of different components, all other parameters being the same, affected COPs. COP is also affected by temperature changes in the heat exchangers. According to TechXplore:

 

The composition of the refrigerant blend can be varied to cater to different applications. This is a key benefit for companies: instead of having to redesign the entire heat pump whenever they need a different temperature, they can simply modify the mixture, which is much simpler and cheaper.”

 

The mixture itself consists of a traditional refrigerant and one further component. The temperature profile of the heat pump is dictated by the ratio of these two ingredients.”

 






Thus, it seems likely that industrial heat pumps utilizing refrigerant blends to increase flexibility and allow the pumps to be used for multiple industrial processes simultaneously, will be a future trend that will improve overall efficiency.

 

 

Case Study – Retrofitting an Industrial Cleaning Machine with a Propane Refrigeration Circuit

     New research from Fraunhofer-Institut für Solare Energiesysteme ISE in Germany, provided by TechXplore, shows that adding a propane refrigeration circuit to an industrial cleaning machine can save considerable electricity, CO2 emissions, and water. Since the two processes of the cleaning machine, cleaning and drying, are done at different temperatures it provides an ideal situation for a heat pump to be utilized for efficiency. The researchers designed a refrigerant system with propane that was below the allowed maximum limit of 150 grams of propane due to safety laws regarding flammability. TechXplore noted that the propane refrigerant system “is also promising in other processes that operate in a similar temperature range (50°C–70°C), such as large dishwashers in canteens.”

 

 

References:

Industrial heat pumps: Five considerations for future growth. McKinsey & Company. March 19, 2024. Industrial heat pumps: Five considerations for growth | McKinsey

Electrifying industry with flexible heat pumps—a new approach may help companies generate carbon-free process heat. Christoph Elhardt. Tech Xplore. June 12, 2024.  Electrifying industry with flexible heat pumps—a new approach may help companies generate carbon-free process heat (msn.com)

Large-scale industrial heat pumps: Proven high and low temperature industrial heat pumps for up to 150°C and 70 MWth. Siemens Energy. Heat pumps (siemens-energy.com)

Think big! Large heat pumps for climate-neutral district heating networks. Siemens Energy. February 16, 2024. Large heat pumps for climate-neutral district heating networks (siemens-energy.com)

A comprehensive review on advances and applications of industrial heat pumps based on the practices in China. Jing Zhang, Hong-Hu Zhang, Ya-Ling He, Wen-Quan Tao. Applied Energy Volume 178. September 15, 2016, pages 800-825. A comprehensive review on advances and applications of industrial heat pumps based on the practices in China - ScienceDirect

12 Types of Industrial Heat Pumps for High-Temperature Applications. Thermal Engineering. May 25, 2024. 12 Types of Industrial Heat Pumps for High-Temperature Applications (thermal-engineering.org)

Heat pump with propane refrigeration circuit developed for industrial applications. Claudia Hanisch. Tech Xplore. June 2024. Heat pump with propane refrigeration circuit developed for industrial applications (msn.com)

High-glide refrigerant blends in high-temperature heat pumps: Part 1 – Coefficient of performance. Leon P.M. Brendel, Silvan N. Bernal, Philip Widmaier, Dennis Roskosch, Cordin Arpagaus, André Bardow, and Stefan S. Bertsch. International Journal of Refrigeration. Volume 165. September 2024, Pages 84-96. High-glide refrigerant blends in high-temperature heat pumps: Part 1 – Coefficient of performance - ScienceDirect

 

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