When considering
low-emissions long-haul trucking, there are several advantages of hydrogen fuel
cells compared to lithium battery power. One important one is that fuel cells
are much lighter, up to eight times, than conventional battery tech. This means
that tires will wear much more slowly. Faster fueling times are another
advantage.
Fuel cells convert chemical energy into electricity, similar to battery cells. They do this very efficiently. However, they operate at high temperatures, which can cause problems.
Scandium, as a dopant, in combination with other materials, is
showing promise that it can lead to lower operating temperatures in solid oxide
fuel cells (SOFCs). Scandium-enhanced SOFCs have already succeeded in reducing
operating temperatures from 900 °C to 600-800 °C. The new discovery with dopants
allows them to potentially cut that to as low as 300 °C, which will have many
benefits. Catalyst degradation has been an ongoing issue for fuel cells, but
new research suggests that those problems will soon be overcome in a big way,
and fuel cells will be enabled with ultra-long lifespans. Platinum alloy
catalysts have been the norm, but can degrade faster than desired and lose
efficiency through time. New research shows that catalysts made from ultrafine
platinum nanoparticles in graphene pockets can eliminate nearly all of that degradability,
with simulations suggesting that they can cycle for 200,000 hours. That is
about 23 years if it were cycling 24 hours a day!
Scandium Dopants Add to Scandium’s SOFC Benefits
Scandium is a very sought-after rare earth element. Unfortunately, the current supply of it, along with the processing/refining capacity of it, is just about 100% controlled by China. That keeps its price up for others but also down since China heavily subsidizes its REE sector. There are new sources being developed in the U.S. in mining projects, but I am unsure about processing. Scandium has been key in reducing the operating temperatures of SOFCs from 900 deg C to 600-800 deg C, and new research suggests that adding Scandium as a dopant along with certain other materials can reduce efficient operating temperatures down to 300 deg C. This would be a very good improvement.
Below are two lists of previous improvements
afforded by scandium in SOFCs.
The new research at Kyushu
University in Japan shows that cubic perovskite oxides with heavy scandium
doping can overcome limitations caused by proton trapping. The materials with
perovskite structures utilized are barium stannate (BaSnO3) and barium titanate
(BaTiO3), and when scandium is substituted become BaSn0.3Sc0.7O3–δ and
BaTi0.2Sc0.8O3–δ. The materials were found to be chemically stable at 300 deg
C, where the scandium can yield the benefits of lowering SOFC operating
temperature. Basically, the experiments show that the required proton
conductivity can be achieved at 300 deg C with the scandium dopants added to
the materials. The researchers expect that the development of low-cost,
low-temperature SOFCs will greatly accelerate the practical application of
these devices. Lower materials costs are a big factor and could make
consumer-level SOFC devices affordable.
According to TechXplore:
"Structural analysis and molecular dynamics
simulations revealed that the Sc atoms link their surrounding oxygens to form a
'ScO₆ highway,' along which protons travel with an unusually low migration
barrier. This pathway is both wide and softly vibrating, which prevents the
proton-trapping that normally plagues heavily doped oxides," explains
Yamazaki. "Lattice-dynamics data further revealed that BaSnO₃ and BaTiO₃
are intrinsically 'softer' than conventional SOFC materials, letting them
absorb far more Sc than previously assumed."
"Beyond fuel cells, the same principle can be
applied to other technologies, such as low-temperature electrolyzers, hydrogen
pumps, and reactors that convert CO₂ into valuable chemicals, thereby
multiplying the impact of decarbonization. Our work transforms a long-standing
scientific paradox into a practical solution, bringing affordable hydrogen
power closer to everyday life," concludes Yamazaki.
Below are the paper's abstract and a figure from it.
Ultrafine Platinum Nanoparticles in Graphene Pockets as
Catalysts
New research at UCLA’s
Samueli School of Engineering, led by engineering professor Yu Huang, suggests
that a 200,000-hour cycling life can be achieved for SOFCs by making a new kind
of catalyst for the SOFC chemical reaction. Currently, platinum alloys are used
as catalysts. In 2024, this team announced that they had developed a new
catalyst that could double the DOE’s target for fuel cell lifespan of 8,000
hours or 150,000 miles for an SOFC hydrogen vehicle. The research suggested
they could reach 15,000 hours or nearly 300,000 miles. That research involved
using cobalt-oxide molecules inside shells of platinum atoms. Now, a much
greater potential improvement has been announced. The new design utilizes pure
platinum, a graphene-protective layer, and porous carbon support. This new
design overcomes the DOE’s target for 2050 by seven times. The result is that
the new catalyst can achieve the same power as lithium-ion batteries at just
one-eighth the weight. This result can be especially relevant for heavy-duty
vehicles such as long-haul trucks. It can also mitigate the problem of
accelerated tire wear in battery EVs. The graphene-encased nanoparticles were
then nested inside the porous structure of Ketjenblack, a powdery carbon
material that is very pure and has enhanced conductivity.
“Heavy-duty fuel cell systems must withstand harsh
operating conditions over long periods, making durability a key challenge,”
said Huang, who holds the Traugott and Dorothea Frederking Endowed Chair at
UCLA Samueli. “Our pure platinum catalyst, enhanced with a graphene-based
protection strategy, overcomes the shortcomings of conventional platinum alloys
by preventing the leaching of alloying elements. This innovation ensures that
the catalyst remains active and robust, even under the demanding conditions typical
of long-haul applications.”
The research involved
stress-testing and simulations to arrive at the 200,000-hour number and showed
a power loss after that simulated time period of less than 1.1%. Below are the
abstract of the paper and a depiction of the new catalyst structure.
References:
U.S.
hydrogen car boasts fuel cell life of 200,000 hours. Alexander Clark. Morning Overview.
September 4, 2025. U.S.
hydrogen car boasts fuel cell life of 200,000 hours
Breakthrough
US hydrogen fuel cell promises 200,000-hour life with minimal power loss. The
new catalyst lost less than 1.1 percent power after 90,000 test cycles, far
surpassing the U.S. Department of Energy’s 30,000-hour target. Georgina
Jedikovska. Interesting Engineering. April 29, 2025. US’
new hydrogen fuel cell shows 1.1% power loss after 90,000 cycles
UCLA
Breakthrough Extends Fuel Cell Lifespan Beyond 200,000 Hours, Paving the Way
for Clean Long-Haul Trucking. UCLA Samueli School of Engineering. April 25,
2025. UCLA
Breakthrough Extends Fuel Cell Lifespan Beyond 200,000 Hours, Paving the Way
for Clean Long-Haul Trucking | UCLA Samueli School Of Engineering
Pt
catalyst protected by graphene nanopockets enables lifetimes of over 200,000 h for heavy-duty fuel cell
applications. Zeyan Liu, Bosi Peng, Yu-Han Joseph Tsai, Ao Zhang, Mingjie Xu,
Wenjie Zang, XingXu Yan, Li Xing, Xiaoqing Pan, Xiangfeng Duan & Yu Huang. Nature
Nanotechnology. Volume 20, pages 807–814. March 24, 2025. Pt catalyst protected
by graphene nanopockets enables lifetimes of over 200,000 h for heavy-duty fuel cell
applications | Nature Nanotechnology
Ketjenblack
EC-600JD. Product Line Polymer additives. Nouryon. Ketjenblack
EC-600JD Electroconductive carbon black
Scandium
superhighway paves way for low-temperature hydrogen fuel cells. Science X staff.
Tech Xplore. August 8, 2025. Scandium
superhighway paves way for low-temperature hydrogen fuel cells
Mitigating
proton trapping in cubic perovskite oxides via ScO6 octahedral networks. Kota
Tsujikawa, Junji Hyodo, Susumu Fujii, Kazuki Takahashi, Yuto Tomita, Nai Shi,
Yasukazu Murakami, Shusuke Kasamatsu & Yoshihiro Yamazaki. Nature Materials.
August 8, 2025. Mitigating
proton trapping in cubic perovskite oxides via ScO6 octahedral networks |
Nature Materials
UCLA-Led
Research Doubles DOE Fuel Cell Lifetime Target with New Catalyst Material.
UCLA Samueli School of
Engineering. August 14, 2024. UCLA-Led
Research Doubles DOE Fuel Cell Lifetime Target with New Catalyst Material |
UCLA Samueli School Of Engineering
USE OF
SCANDIUM IN SOFCs. Suniway. SUNIWAY_Scandium_SOFC.pdf
Scandium
Oxide: Key Material for Next-Generation Solid Oxide Fuel Cells (SOFCs).
Stanford Advanced Materials. Scandium
Oxide: Key Material for Next-Generation Solid Oxide Fuel Cells (SOFCs) |
Scandium `
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