In 2024, Australian researchers from Curtin University and
Velox Energy Materials developed a means to store hydrogen in solid form as
sodium borohydride (NaBH4) powder for safe and cheaper export. Nanotechnology
researchers, based at Deakin University's Institute for Frontier Materials,
originated the process of powdered hydrogen storage via mechanochemistry. NaBH4
was previously used in dyeing and paper-making industries. Adding water to the
hydrogen-infused NaBH4 powder causes it to release the hydrogen, which would
happen at the export destination. After the hydrogen is exported and
released, it yields a powdered byproduct, sodium borate, or sodium
metaborate, which can then be chemically changed back into NaBH4, creating a
circularity in the total process.
Typically, hydrogen to be
exported is either compressed into a gas or cooled to very low temperatures to
form liquid hydrogen. Both of these methods involved large energy inputs.
Mechanochemistry and Solid-State Hydrogen
According to Good News
Network, the project proposal was sent to the Australian Renewable Energy Agency
(ARENA) in 2024:
“…outlined that on a specialized tanker ship, liquid H2
costs around $10.1 per kilogram to ship, while if stored in an ammonia form, it
falls to $7.9 per kilo, but becomes toxic.”
“In complete contrast, hydrogen stored as sodium
borohydride costs 15% less than ammonia form, and can be shipped in much
greater quantities aboard regular container ships.”
According to Sustainability
Times:
“Previously, the cost and complexity of recycling sodium
metaborate back into sodium borohydride posed a hurdle. However, recent
innovations have made this process more affordable, opening new avenues for
hydrogen transportation and storage. This development not only reduces the cost
of hydrogen export but also enhances safety, making it a viable global energy
solution.”
The cool AI-generated graphic
below shows what the process might look like:
Australia plans to produce
330,000 tons of green hydrogen annually by 2030, scaling up to 550,000 tons by
2040. This will be produced by electrolyzers powered by the country’s
significant solar and wind resources. A ton of NaBH4 can produce about 213kg of
H2, which means Australia’s long-term plans call for 2.58 million tons of
NaBH4, which is considered to be feasible.
“The Kotai Hydrogen Project, a collaborative effort with
Curtin University and ARENA, is a $16.47 million initiative aimed at scaling
sodium borohydride production and ensuring continuous hydrogen generation.”
“Set to run until 2029, this pilot program is a
game-changer in hydrogen production and transportation.”
Source: Sustainability Times
Mechanochemistry is a
recently coined term. According to a 2022 article in New Atlas explaining the
discovery of the possibilities of solid-state hydrogen, mechanochemistry refers
to
“… chemical reactions that are triggered by mechanical
forces as opposed to heat, light, or electric potential differences. In this
case, the mechanical force is supplied by ball milling – a low-energy grinding
process in which a cylinder containing steel balls is rotated such that the
balls roll up the side, then drop back down again, crushing and rolling over
the material inside.”
The chemical salts used in
the reactions are very stable and non-reactive in normal circumstances. There
are some other potential applications for this technology. According to New
Atlas’s 2022 article, it could be used to separate hydrocarbon gases from crude
oil using less than 10% of the energy of doing it with cryogenics, which is
energy-intensive. They are also working on the process to separate out
different gases, using different powders.
“Different gases, they found, are absorbed at different
milling intensities, gas pressures and time periods. Once the first gas is
absorbed into the powder, it can be removed, and the process can be re-run with
a different set of parameters to trap and store the next gas. Likewise, some
gases are released from the powders at higher temperatures than others,
offering a second way to separate gases if they're stored together.”
The savings in cost, energy,
and emissions mean that the process could be commercialized for several
different gas separation processes. They were then also looking at using the
powdered hydrogen directly for H2-enabled transport, but this would require
more tweaks, but this would require a suitable tank, and a way to control the
reaction of releasing the H2.
Below are some details from the 2024
Project Proposal:
References:
Australia’s
Revolutionary Hydrogen Powder Is Easier and Cheaper to Use for Clean Energy. Andy
Corbley. Good News Network. August 1, 2025. Australia’s
Revolutionary Hydrogen Powder Is Easier and Cheaper to Use for Clean Energy
Mechanochemical
breakthrough unlocks cheap, safe, powdered hydrogen. Loz Blain. New Atlas. July
18, 2022. Mechanochemical
breakthrough unlocks cheap, safe, powdered hydrogen
Hydrogen
export using a powder. Curtin University: Craig Buckley, Mark Paskevicius,
Peter O Conghaile, Terry Humphries, Peta Ashworth Velox Energy Materials: Mike
Griffiths, Nicole Morcombe, Simon Coyle. June 2024. PowerPoint
Presentation
“This
Is a Weapon, Not Progress”: Australian Whistleblower Blasts 550 Million Kg of
Hydrogen Powder as a Global Power Grab. Australia is poised to revolutionize
the global energy landscape with its groundbreaking production of hydrogen in
powder form, a development that promises to enhance safety, efficiency, and
sustainability in energy transportation and storage. Rosemary Potter.
Sustainability Times. July 25, 2025. “This
Is a Weapon, Not Progress”: Australian Whistleblower Blasts 550 Million Kg of
Hydrogen Powder as a Global Power Grab - Sustainability Times
No comments:
Post a Comment