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Thursday, January 23, 2025

Radon Gas: Dangers, Exposure, Geochemistry, Mitigation Methods, and a New Map of Geographic Concentrations



Radon Dangers: Deadly Lung Cancer, Other Cancers, and Stroke

     According to Phys.org:

Radon gas pollution is the second leading cause of lung cancer in the United States, claiming an estimated 21,000 lives per year (220,000 globally), with exposure linked to multiple other risks such as breast cancer, stroke and stomach cancer.”

At radon concentrations above 148 Bq/m3, the EPA recommends mitigation efforts.  The World Health Organization set a new recommended radon reference level in 2009 of 2.7 pCi/L for residences and the U.S. The President’s Cancer Panel issued its “Reducing Environmental Cancer Risk: What We Can Do Now” in 2010. It encourages the EPA to consider lowering its current “action level” (the level at which remedial action is recommended) of 4 pCi/L for radon exposure.

Phys.org:

Regulations adopted in 35 states have mandated radon measurement and disclosure during property transactions, with tens of millions being recorded in the last few decades. The accumulated data provides an opportunity for revisiting the distribution of radon risk around the country.”

Radon gets into the lining of the lungs and over time causes lung cancer. Radon-sourced lung cancer has also been identified at high levels among underground miners. Children are especially vulnerable to lung effects from radon. According to Web MD:

Children may be especially vulnerable to radon’s health risks. That’s because their lungs have a different size and shape compared to those of adults. Children also breathe at a faster rate. Those factors mean that children get higher doses of radon when they breathe it in. It remains unclear whether this leads to higher rates of lung cancer, but some experts estimate that children could have twice the risk of lung cancer as adults exposed to the same amount of radon.”

The vast majority of exposure to dangerous levels of radon gas occurs in homes. According to the EPA, “Radon in homes causes more deaths than fires, drownings, and airplane crashes combined.” More people die from lung cancer than any other cancer and radon gas is the second highest cause of cancer after smoking, making it the number one lung cancer cause for non-smokers. RadonSeal suggests that people who spend more time in basements where radon leaks in are more likely to develop cancer than those who don’t. The damage from radon decay products is concentrated on the bronchial epithelial cells in the immediate area where alpha particles are trapped or deposited. Radon gas also enters the bloodstream where it can be trapped and possibly lead to other cancers including breast cancer and leukemia. There is also a possibility of radon causing genetic damage.

     There is some controversy about the risks of low-level radiation. However, the EPA radon gas action limits are considered to be valid by most scientists. RadonSeal notes that it is likely radon that causes cancer among smokers as well since it it the only known constituent that has caused cancer by itself in the lab. The EPA Radon Potential Map is shown below:






Lung cancer rates among men kept climbing from a rarity in 1930 (4/100,000 per year) to the No. 1 cancer killer in 1980 (72/100,000) in spite of an almost 20 percent reduction in smoking. But during the same period, the level of polonium-210 in American tobacco had tripled. This coincided with the increase in the use of phosphate fertilizers by tobacco growers – calcium phosphate ore accumulates uranium and slowly releases radon gas.”

     Humans spend 70-75% of their time indoors, children even more. Humans receive more radiation from radon than from all other sources combined. This is because radon is a radioactive gas.  

 





Radon Geochemistry

     Radon gas is generated in the subsurface by the radioactive decay of the element radium, which is itself derived from the decay of the element uranium. Radon gas further decays to solid lead as shown below.






     The U.S Geological Survey (USGS) notes:

Radon levels in outdoor air, indoor air, soil air, and ground water can be very different. Outdoor air ranges from less than 0.1 pCi/L to about 30 pCi/L, but it probably averages about 0.2 pCi/L. Radon in indoor air ranges from less than 1 pCi/L to about 3,000 pCi/L, but it probably averages between 1 and 2 pCi/L. Radon in soil air (the air that occupies the pores in soil) ranges from 20 or 30 pCi/L to more than 100,000 pCi/L; most soils in the United States contain between 200 and 2,000 pCi of radon per liter of soil air. The amount of radon dissolved in ground water ranges from about 100 to nearly 3 million pCi/L.”

Uranium in rocks is the source of radon gas. All rocks have some uranium. The average is between 1 and 3 parts per million (ppm). In general, the uranium content of a soil is dependent on the uranium content of the parent rock from which the soil is derived. Some types of rocks have higher than average uranium content, including light-colored volcanic rocks, granites, dark shales, sedimentary rocks that contain phosphate, and metamorphic rocks derived from these rocks. These rocks and their corresponding soils could have as much as 100ppm of uranium. These rocks of higher uranium content occur in various parts of the U.S. Buildings in areas with these rocks of higher uranium content tend to have higher radon gas levels as well, but there are exceptions. One reason for less radon gas in high uranium areas is better sealing of the building against entry of gases from the ground. The graphic below shows that most of the radon gas generated by rocks remains in the mineral grains. Between 10 and 50% of the radon gas typically escapes into the pore spaces of the rock. If the pore space is dry the gas may become embedded in a nearby mineral grain. If the pore space contains water the radon is more likely to remain in that pore space.  






     Radon gas will travel upward, especially through more permeable soils. It may become embedded in the soil and then likely decay to lead, or it may escape into the atmosphere. Because gases move less readily in impermeable soils like clays, they may become trapped or embedded by the impermeable layer. Thus, the layer that effectively seals in the gas. Similarly, foundation sealing is one way that radon gas is prevented or mitigated. Radon moves slower in water than in air space. On average it moves 1 inch in water-saturated soil and 6 feet in dry soil in the time it takes for most of it to decay. Thus, radon tends to travel faster and further in dry soils. Thus, an important variable for radon gas concentration is the permeability of the soil or rock. Intergranular permeability and especially fracture permeability in rock can help maximize total gas entry into a building as can dry soil.

USGS:

For these reasons, homes in areas with drier, highly permeable soils and bedrock, such as hill slopes, mouths and bottoms of canyons, coarse glacial deposits, and fractured or cavernous bed- rock, may have high levels of indoor radon. Even if the radon content of the air in the soil or fracture is in the normal range (200-2,000 pCi/L), the permeability of these areas permits radon-bearing air to move greater distances before it decays and thus contributes to high indoor radon.”

 

Radon entry into buildings

     “Radon moving through soil pore spaces and rock fractures near the surface of the earth usually escapes into the atmosphere. Where a house is present, however, soil air often flows toward its foundation for three reasons: differences in air pressure between the soil and the house, the presence of openings in the house's foundation, and increases in permeability around the basement (if one is present).”

     “In constructing a house with a basement, a hole is dug, footings are set, and coarse gravel is usually laid down as a base for the basement slab. Then, once the basement walls have been built, the gap between the basement walls and the ground outside is filled with material that often is more permeable than the original ground. This filled gap is called a disturbed zone.”

     “The air pressure in the ground around most houses is often greater than the air pressure inside the house. Thus, air tends to move from the disturbed zone and gravel bed into the house through openings in the house's foundation. All house foundations have openings such as cracks, utility entries, seams between foundation walls and slabs, sumps, permeable foundation materials, and uncovered soil in crawl spaces and basements.”

     “Most houses draw less than one percent of their indoor air from the soil; the remainder comes from outdoor air, which is generally quite low in radon. Houses with low indoor air pressures, poorly sealed foundations, and several entry points for soil air, however, may draw as much as 20 percent of their indoor air from the soil. Even if the soil air has only moderate levels of radon, levels inside the house may be very high.”
















     It is important that the mitigation system does not cause the collected and further concentrated radon gas to be sucked back into the home. EPA recommendations to prevent this are shown below.






     Radon may also be present in water, particularly in groundwater. Municipal water systems may aerate the water, and gases can also bubble out through time so that any radon gas is usually gone before it reaches consumers. It is present in very small amounts in common building materials – rock, brick, and concrete.

      In order to evaluate the potential for dangerous concentrations of radon gas, one should first determine the proximity to source rocks via geology. Next, any other post-deposition events that redistributed rock should be understood. The permeability of the spaces between the source rocks and the surface should be determined. And finally, soil saturation should be determined. 







     Below, from the 1992 USGS book on the Geology of Radon, are two sections of an aero-radioactivity map of the U.S. that measures surface uranium concentrations via aircraft flying grid patterns. Superimposed on that are shown different areas where radon gas has been found in higher concentrations along with the different geological sources and additional factors. For instance, the Ohio Shale which outcrops in central Ohio was redistributed by the movement of glaciers so that the radioactivity was spread over a larger area of the state. It is a radon gas hotspot based on direct indoor measurements nationwide. It is one of the hotspots in a populated area as well.

 











Radon Sampling in Soils, Homes, and Buildings

Soil Vapor Sampling

     The way to gather data about radon gas is to gather and analyze soil vapor samples. Soil vapor contains a composite of different soil gases such as CO2 and biological decay gases.   Measurement of radon in soils is similar to measuring it in buildings. Both methods measure the alpha particles produced by the decay of the radon in the air. One method, designed for long-term sampling at intervals is shown below.




USGS:

Soil-air methods require specialized equipment because soil-air data are sensitive to many conditions and factors, such as the depth of measurement. Radon levels vary widely in the top 2 to 3 feet of soil because of variations in soil moisture and the amount of radon that escapes to the atmosphere. Making measurements at 3 feet or deeper avoids many of the problems related to near-surface conditions, but it may be difficult in some soils.”

USDA -Natural Resources Conservation Service Soil Surveys now often contain important data about soil permeability, which can be used to high-grade vulnerable areas.

USGS:

By careful examination and correlation, scientists can evaluate the effects of varying geology and soils on actual readings of indoor radon. The indoor radon information can be used as an additional aid to create a radon potential map or it can be used as a way of expressing the radon potential of areas mapped by the geologist. However, differences in house construction also can cause variations in the indoor radon levels.”

 

Home or Building Sampling: Short-Term, Long-Term, In-Water Testing, and DIY Test Kits

     Residential radon gas sampling can be done with do-it-yourself test kits. There is short-term testing and long-term testing. As Radon Test Kits.com notes long-term tests are much more accurate and reliable than short-term tests. However, short-term tests can indicate whether long-term tests are warranted.   






     As shown below, radon levels can vary drastically between short-term and long-term testing. In general, short-term tests have a wider range of results. The reasons the readings vary so much in time are discussed below by Radon Test Kits.com:

During a single day, the concentration of radon gas in indoor air varies widely and may easily double or triple. Moreover, it fluctuates greatly from day to day, week to week, and season to season.”

Radon gas is drawn from the ground into homes by differences in concentration, air pressure, and temperature. This force largely depends on the weather and ground conditions outdoors. The indoor radon level is thus affected by barometric pressure, strong winds, rain-soaked ground, snow cover, the season, heating and A/C systems, house construction, open windows, etc.”

     The variability and ranges in concentrations between short-term and long-term tests is shown for a home over a two-year period in the graph and table below. Long-term tests are typically done over a period of 3 to 12 months, evening out the wild daily, weather-dependent, and season swings in concentrations often encountered with short-term tests.








     The EPA has developed standards, protocols, and strategies for radon testing. Below are some testing methods and strategy flow charts from an early EPA manual.  

 









Radon Prevention and Mitigation Methods

     One method of radon prevention and mitigation is deep-penetrating concrete sealers for basements. Company RadonSeal has been the leader in providing these sealing products, also called RadonSeal. They have two types: standard basement dealer for poured concrete less than 20-years and outdoor concrete less than 2-years old, and a higher strength sealer used for more porous concrete and blocks. Recommended for concrete and cinder blocks, poured concrete older than 20-years, and outdoor concrete older than 2-years. They note that it “contains ZERO VOCs, is solvent-free, does not off-gas, is non-toxic, and is a noncorrosive concrete sealer.” RadonSeal is also very good at waterproofing and should be applied especially in areas where radon is a concern. It also protects and extends the life of basement concrete. It should be applied on walls and floors before finishing or painting. The benefits of RadonSeal are shown below.

 






     Aside from concrete basement sealing, other radon mitigation methods can be classified as fan-based or passive. Different methods are suited to different applications and materials. The table below shows a variety of radon mitigation strategies, some based on fans and ventilation, some based on suction and depressurization, and some based on preventing gas entry such as sealers and caulking. Of course, utilizing both sealing and ventilation systems can be a comprehensive mitigation solution. A plastic vapor barrier under a house or in a crawl space can retard or slow radon gas movement but it still diffuses.

 

 








A New U.S. National Map of Radon Concentrations

     Researchers from Harvard T.H. Chan School of Public Health have assembled a national database with millions of multi-day indoor radon measurements from 2001 to 2021. This enables an updated and improved nationwide map of radon gas concentration levels, as shown below. The findings from the study include:

25% of the U.S. population may be exposed to radon concentrations exceeding 148 Bq/m3, a level associated with cancer risks.”

However, there is debate about the level of radon that is dangerous so those numbers may overestimate the dangers.

     The new map is based on 6 million direct measurements, many required for property sale disclosures.

 






Geogenic Radon Potential Maps and Risk Assessment Models

     A February 2024 paper in Science of the Total Environment offered new perspectives on radon risk assessment based on machine learning analysis of the different variables affecting indoor radon exposure. The authors developed a radon hazard indicator based on machine learning number crunching the different variables. They call it the Geogenic Radon Potential (GRP).

The GRP is characterised by the interaction of three natural processes

• Background Radon Source (BRS) represents the process that produces Rn through the natural decay of uranium (U) and thorium (Th) (220Rn), which are present in rocks and soils.

• Tectonically Enhanced Radon (TER, Benà et al., 2022) accounts for processes that allow radon to migrate more easily towards the surface through permeable pathways (e.g., faults and fractures in the crust) from deeper sources, caused by increased stress and pressure conditions associated with tectonic activity.

• Surface Radon Exhalation (SRE) is the process by which radon gas is released from the ground into the atmosphere. SRE considers variables affecting radon movement in the shallow soil up to the soil/atmosphere interface (e.g., land morphology, soil permeability, atmospheric pressure, humidity, and temperature). This quantity of radon represents the amount that could potentially enter buildings, although BRS and TER are the dominant geological radon sources.

The authors developed a radon hazard indicator based on machine learning number crunching the different variables. They call it the Geogenic Radon Potential (GRP). The first graph below shows the risk model. Below in the second graph are the different variables that were analyzed in the modeling to derive the mapping. I have done similar types of composite mapping in oil & gas geology, with varying weights and emphases attributed to each variable. Another way of graphing the attributes of the model is via a SHAP diagram as shown in the third figure below.








     This method of mapping can isolate areas with high hazard risks, known as Radon Priority Areas (RPAs). The maps below are from the target study area of the project in the Pusteria Valley in the Alps of Italy and Austria.

 

 







References:

 

Comparison Of Radon Mitigation Methods. RadonSeal. Radon Mitigation Methods - Comparison

Radon: How It Can Affect Your Health. Matt McMillen and  Zilpah Sheikh, MD. Web MD. August 7, 2024. Radon Gas Exposure & Poisoning: Symptoms, Health Effects, Prevention

The Geology of Radon. James K. Otton. U.S. Geological Survey. 1992. report.pdf

A new perspective in radon risk assessment: Mapping the geological hazard as a first step to define the collective radon risk exposure. Eleonora Benà, Giancarlo Ciotoli, Eric Petermann, Peter Bossew, Livio Ruggiero, Luca Verdi, Paul Huber, Federico Mori, Claudio Mazzoli, and Raffaele Sassi. Science of The Total Environment. Volume 912, 20 February 2024, 169569. A new perspective in radon risk assessment: Mapping the geological hazard as a first step to define the collective radon risk exposure - ScienceDirect

How Radon Gas Sneaks into Homes. RadonSeal. Radon in Homes from Soil, Water and Even Air.

There is no Safe Radon Level! RadonSeal. Radon Levels: None is safe in Homes | RadonSeal

Radon Standards of Practice. U.S. EPA. Radon Standards of Practice | US EPA

How Radon Causes Lung Cancer. RadonSeal. How Radon Gas Endangers People in Their Own Homes

National Consensus Standards for Every Building Type. AARST Consortium on National Radon Standards. AARST Radon Standards

Protocols For Radon And Radon Decay Product Measurements In Homes. U.S. EPA. May 1993. PROTOCOLS FOR RADON AND RADON DECAY PRODUCT MEASUREMENTS IN HOMES

Improved radon gas mapping finds nearly 25% of Americans living in highest risk areas. Justin Jackson. Phys.org. January 21, 2025. Improved radon gas mapping finds nearly 25% of Americans living in highest risk areas

High-resolution national radon maps based on massive indoor measurements in the United States. Longxiang Li, Brent A. Coull, Carolina L. Zilli Vieira, and Petros Koutrakis. PNAS. 122 (3) e2408084121. January 14, 2025. High-resolution national radon maps based on massive indoor measurements in the United States | PNAS

Detailed Radon County Statistics. Ohio Department of Health. County+Statistics+up+to+September+2020.pdf

Geometric Mean of Indoor Radon Concentrations in Ohio Counties. Ohio Department of Health. Ohio+Map+of+Concentration.pdf

Radon and Radioactivity – Facts and Controversies. RadonSeal. Amazing Facts and Arguments about Radon and Radioactivity

Are Short-Term Radon Test Kits Worth It? Freeradontestkits.com. Are Short-Term Radon Test Kits Accurate? Are Long-Term Test Kits Better?

DIY Teat Kits. RadonSeal. Radon Test Kits Archives | RadonSeal

RadonSeal Deep-Penetrating Concrete Sealers. RadonSeal. Basement Sealer - Radon Mitigation and Waterproofing

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